Electronic and Ionic Transport in Polymers

Abstract

A new electroactive and soluble polymer, based on nickel bisdithiolene linkages along the polymer main chain, has been prepared. This polymer, poly(bis-(4-oxystyryldithiolene)nickel) (PBOSD-Ni), can be dissolved in both aqueous and organic solvents in the reduced form. UV-VIS spectra show features typical to comparable nickel bisdithiolene complexes and the (NiL2(2-) yields (NiL2)(1-) yields (Nil2)(0) oxidation states are observed electrochemically.

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Document Details

Document Type
Technical Report
Publication Date
Jul 12, 1988
Accession Number
ADA197108

Entities

People

  • Fei Wang
  • John R. Reynolds

Organizations

  • University of Texas at Arlington

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Coordination Complexes
  • Electrical Conductivity
  • Electrodes
  • Electron Transfer
  • Macromolecules
  • Metals
  • Oligomers
  • Organic Solvents
  • Oxidation
  • Solvents
  • Spectra
  • Transition Metals
  • Transitions

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Electrochemical Surface Science

Technology Areas

  • Microelectronics