Chemical Agent Simulants for Testing Transparent Materials

Abstract

Transparent polymeric materials undergo physical changes when exposed to chemical warfare agents. The object of this task was to: 1) select candidate liquids to simulate GB, VX and HD effects (three each) and 2) perform three point bend tests to determine critical strain values for cracking/crazing for simulant/transparent polymer materials combinations. The critical strain tests were accomplished using ASTM method D790-80 for stress crazing. The method was modified and enhanced to detect stress crazing via changes in reflection/ diffraction patterns produced with a helium-neon (He-Ne) laser. Four transparent polymer materials were tested; namely, as cast polymethyl methacrylate (PMMA), biaxially stretched PMMA, polycarbonate and polyurethane GAC-590. The critical strain values obtained for the simulant/polymer combinations are presented as a four by nine map that allows easy comparisons as a function of material or simulant. Comparison with actual agent data is possible using this four by nine map. (aw)

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1988
Accession Number
ADA197138

Entities

People

  • Emory W. Sarver
  • Louis Isaacson
  • Paul S. Grasso
  • Randall E. Lewis
  • Shirley A. Liebman

Tags

DTIC Thesaurus Topics

  • Abstracts
  • Chemical Agent Simulants
  • Chemical Compounds
  • Chemical Warfare
  • Chemical Warfare Agents
  • Chemistry
  • Classification
  • Engineering
  • Materials
  • Plastics
  • Polymers
  • Polymethyl Methacrylate
  • Polyurethanes
  • Resins
  • Security
  • Test And Evaluation
  • Vapor Pressure

Fields of Study

  • Materials science

Readers

  • Combustion Dynamics and Shock Wave Physics.
  • Environmental Engineering.
  • Mechanical Engineering/Mechanics of Materials.

Technology Areas

  • Directed Energy