Ultrathin Polymer Films for Microlithography

Abstract

Ultrathin (14 to 22 nm) poly(methylmethacrylate) (PMMA) films prepared by both spin-casting and Langmuir-Blodgett (LB) techniques and novolac films prepared by spincasting have been explored as high resolution electron- beam resists. One-eighth micron lines-and-spaces patterns (equal to the smallest beam diameter available) have been achieved by using a Perkin Elmer MEBES I pattern generation system as the exposure tool, and the definition of 45 nm features has recently been achieved by using a high resolution electron beam lithography system. The etch resistance of such films is sufficiently good to allow patterning of a chromium film suitable for photomask fabrication. The most surprising result has been that the pinhole densities in 14.3 nm LB PMMA film and 22 nm spin-cast novolac film are only a few per sq. cm., considerably lower than the density in spin-cast PMMA films of comparable thickness. Keywords: Polymethyl methacrylates.

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Document Details

Document Type
Technical Report
Publication Date
Jul 13, 1988
Accession Number
ADA197298

Entities

People

  • C. C. Fu
  • C. W. Frank
  • D. R. Alee
  • P. Maccagno
  • S. W. Kuan

Organizations

  • Stanford University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Engineering
  • Chemical Synthesis
  • Chemistry
  • Chromium
  • Diameters
  • Electron Beam Lithography
  • Electron Beams
  • Engineering
  • Fabrication
  • Fatty Acids
  • Films
  • High Resolution
  • Lithography
  • Materials
  • Measurement
  • Polymeric Films
  • Polymers

Readers

  • Nanofabrication and Microfabrication.
  • Thin Film Deposition Science.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene
  • Space