Phase Separation of Liquid Crystals in Polymers

Abstract

New optoelectronic materials based on polymer dispersed liquid crystals (PDLC) show great potential for application in displays, temperature sensors, optical computing and for solar energy control. We report liquid crystals, thermoset or thermoplastic materials. PDLC materials may be formed by several different processes. The liquid crystal may be dissolved in low molecular weight polymer precursors, in a thermoplastic melt or with a thermoplastic in a common solvent. Subsequent polymerization, cooling of the polymer melt or solvent evaporation lead to liquid crystal immiscibility, droplet formation and growth, and polymer gelation. The optoelectronic properties of these materials are affected by the droplet morphology. Specific examples are presented for each of these processes and it is demonstrated how the droplet morphology for density, and thus device performance, can be controlled by each method.

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Document Details

Document Type
Technical Report
Publication Date
Jul 11, 1988
Accession Number
ADA197459

Entities

People

  • John L. West

Organizations

  • Kent State University

Tags

Communities of Interest

  • Sensors

DTIC Thesaurus Topics

  • Air Flow
  • Crystals
  • Evaporation
  • Films
  • Flow Rate
  • Gelation
  • Liquid Crystals
  • Materials
  • Phase
  • Phase Diagrams
  • Phase Separation
  • Phase Transformations
  • Polymers
  • Solvents
  • Transition Temperature
  • Transitions
  • United States

Fields of Study

  • Materials science

Readers

  • Combustion and Flow Dynamics.
  • Nanocomposite Materials Science
  • Polymer Science and Engineering.

Technology Areas

  • Microelectronics