Organotin-Induced Hemolysis, Shape Transformation and Intramembranous Aggregates in Human Erythrocytes

Abstract

Organotin compounds examined in this study exhibited a relative order of potency for induction of in vitro hemolysis in human erythrocytes as follows: tri-n-butylin > tri-n-propyltin > tetra-n-butyltin > triphenyltin chloride > tri-n-ethyltin bromide > dibutyltin dichloride > stannous chloride > tri-n-methyltin chloride = butyltin chloride dihydroxide. All of the organotin compounds induced erythrocyte shape transformation from the normal discocyte to an echinocyte and, in addition, triphenyltin chloride, tetra-n-butyltin and tri-n-ethyltin bromide also elicited stomatocyte formation at higher concentrations. Select organotin compounds also formed tin-containing aggregates within the plasma membrane. The relative order of effectiveness for organotin induction of intramembranous aggregates was tri-n-butyltin > tri-n-propyltin > tetra-n-butylin > tri-n-ethyltin bromide, which was based upon the lowest concentration at which they were observed. These results support the previously suggested theory that organotins are membrane effectors because of their comparatively high hydrophobic, lipid partitioning properties. The relatively lipophilic compound, triphenyltin chloride, appeared to be anomalous because it did not readily promote hemolysis or induce the formaiton of intramembranous aggregates in human erythrocytes. A log-linear statistical model demonstrated an association of hemolysis with both tri-n-butyltin aggregate formation and shape transformation. Select organotin compounds should be useful probes in membrane studies because of their numerous effects. Keywords: Toxicity, Reprints.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1987
Accession Number
ADA197901

Entities

People

  • Brian H. Gray
  • Carlyle Flemming
  • Lanfong H. Lee
  • Martin Porvaznik

Organizations

  • Naval Medical Research Center

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Alcohols
  • Birds
  • Blood
  • Cell Biology
  • Cell Membrane
  • Cells
  • Cellular Structures
  • Chemical Synthesis
  • Chemistry
  • Ecology
  • Electron Microscopy
  • Electrons
  • Erythrocytes
  • Microscopy
  • Navy
  • Organometallic Compounds
  • Statistical Analysis

Readers

  • Analytical Chemistry
  • Analytical Mechanics