Radiation Sensitivity of Soluble Polysilane Derivatives: Science and Applications

Abstract

Polysilane derivatives have very unusual electronic properties associated with extensive sigma delocalization along the polymer backbone. Strong electronic transitions which depend on the nature of the substituents, the polymer molecular weight and the conformation of the backbone appear in the UV. These materials are radiation sensitive and are degraded to lower molecular weight fragments upon exposure to light and ionizing radiation. This review attempts to overview the nature of these radiation induced processes and describes some potential applications primarily in the field of microlithography. Keywords: High molecular weight polysilanes; Radiation sensitivity.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1988
Accession Number
ADA198805

Entities

People

  • R. D. Miller

Organizations

  • International Business Machines Corporation (Armonk, NY)

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Abstracts
  • Alkenes
  • Body Weight
  • Chemical Synthesis
  • Chemistry
  • Copolymers
  • Ionization
  • Ionizing Radiation
  • Mass Spectra
  • Materials
  • Molecular Weight
  • Optical Properties
  • Organic Chemistry
  • Polymeric Films
  • Polymers
  • Quantum Yields
  • Radiation

Fields of Study

  • Physics

Readers

  • Nanocomposite Materials Science
  • Nuclear and Radiation Engineering.

Technology Areas

  • Microelectronics