Molecular Design of Novel Discogen Possessing a Semi-Flexible Aryloxytriazine Core

Abstract

Two compounds have been synthesized which exhibit a discotic mesophase. The molecule includes a semi-flexible tris (benzylidene oxyniline) triazine core flanked by just one alkyl substituent at the 4' position of each radial ring. An oxygen links the benzylidene aniline groups to the central triazine ring. Calorimetric measurements and polarizing microscopy observations show the existence of discotic mesophases. This appears to be the first example of a semi-flexible core with only minimal alkyl substituents which still produces a discotic liquid crystalline phase.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Sep 15, 1988
Accession Number
ADA198857

Entities

People

  • J. A. Feldman
  • J. F. Johnson
  • S. J. Huang

Organizations

  • University of Connecticut

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Connecticut
  • Engineering
  • Liquid Crystals
  • Materials
  • Materials Science
  • Measurement
  • Melting Point
  • Microscopy
  • Military Research
  • Optical Properties
  • Phase Diagrams
  • Security
  • United States

Fields of Study

  • Chemistry

Readers

  • Materials Science and Engineering.
  • Organic Chemistry
  • Reinforced Composite Materials