The Metabolites of Fentanyl and its Derivatives

Abstract

Since its introduction in the 1960's, fentanyl has found widespread clinical use as a morphinomimetic narcotic analgesic, primarily in the form of its citrate salt (Sublimaze, Fentanest, Pentanyl). With a potency in rats of almost three hundred times that of morphine, its onset time and duration of action are considerably shorter than that of the naturally occurring opiate. Its safety margin is well over 100 in animal studies. In man, its activity is somewhat attenuated, for example, intramuscular administration of fentanyl in clinical studies has led to potency ratio estimates of 50. These properties have occasioned its popularity in surgical analgesia, especially when combined with a powerful tranquilizer such as droperidol in the technique of neuroleptanalgesia. An extensive literature search identified 15 metabolites for the synthetic opiod fentanyl. Sufentanil and alfentanil had 2 and 3 reported metabolites respectively. Factors determining the metabolic fate of these opiods, as well as the nature and quantity of metabolites isolated, are discussed. Keywords: Opium alkaloids.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1988
Accession Number
ADA199595

Entities

People

  • C. P. Ferguson
  • H. D. Banks

Organizations

  • Edgewood Chemical Biological Center

Tags

DTIC Thesaurus Topics

  • Analgesia
  • Anhydrides
  • Animals
  • Blood
  • Blood-Brain Barrier
  • Chemical Synthesis
  • Chemistry
  • Chromatography
  • Gas Chromatography
  • Mass Spectra
  • Mass Spectrometry
  • Materials
  • Metabolism
  • Metabolites
  • Molecules
  • Opioids
  • Rodents

Readers

  • Child and Adolescent Substance Abuse Science in Autism Spectrum Disorders.
  • Neurotrauma and Rehabilitation Medicine.
  • Toxicology/Environmental Toxicology