An In Situ Infrared Study of the Oxidation of SO(2) on Platinum Electrodes

Abstract

The oxidation of sulfur dioxide on metal electrodes is of interest for its application in a variety of industrial processes, particularly in operations involving degradation of automobile emissions, production of energy, and winning of sulfide ores. The oxidation of sulfur dioxide by electrochemical methods is a complex process in which intermediates and products are formed which strongly adsorb on the electrode surface. A large number of electrochemical investigations have appeared which employ voltammetric techniques to obtain mechanistic information about the process. However, the oxidation process at platinum electrodes is a strong function of electrode pretreatment at cathodic potentials; thus, the electrochemical studies are not all in agreement. Electrodes.

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Document Details

Document Type
Technical Report
Publication Date
Jul 15, 1988
Accession Number
ADA200301

Entities

People

  • C. Koreniewski
  • Stanley Pons
  • W. Mckenna

Organizations

  • University of Utah

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Air Force
  • Chemical Engineering
  • Chemistry
  • Dielectric Gases
  • Electrochemistry
  • Electrodes
  • Engineering
  • Infrared Spectra
  • Materials
  • Military Research
  • New Jersey
  • New York
  • Spectra
  • United States
  • Universities
  • Voltammetry

Fields of Study

  • Chemistry

Readers

  • Electrochemical Surface Science
  • Surface Engineering/Surface Coating Technology.
  • Theoretical Analysis.