The Reactivity of Transition Metal-Silicon Compounds

Abstract

The objective of this work was to synthesize and study early- transition-metal silyl compounds that have the potential to carry out novel chemical transformations and to serve as precursors to solid-state materials containing both silicon and an early-transition-metal. We discovered several routes to new early-transition-metal silyl complexes. These complexes contain - SiMe3, -Si(SiMe3)3 and -SiHMes2 (Mes=mesityl) silyl groups. These new complexes, of scandium, zirconium, hafnium, niobium and tantalum, have been characterized by a variety of spectroscopic techniques, including x-ray crystallography. Reactivity studies with these new complexes establish basic reactivity patterns toward a range of reactants. Unusual reactions that were discovered for these M- Si bonds include: reductive elimination fo silyl groups with chloride, first observation of Carbon Monoxide insertion into a transition-metal-silicon bond, routes to the first stable formylsilane, (Me3Si)3SiCHO, facile ether cleavage following CO/CO coupling by a tantalum-silicon bond, formation of tetrahedral Lewis base adducts of M(eta (2) -COSiR3) silaacyl complexes, insertion of organic carbonyls into a tantalum-silicon bond with nucleophilic silyl group transfer, and facile photochemical and thermal insertions of ethylene into metal-silicon bonds.

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Document Details

Document Type
Technical Report
Publication Date
Aug 08, 1988
Accession Number
ADA200371

Entities

People

  • T. D. Tilley

Organizations

  • University of California, San Diego

Tags

DTIC Thesaurus Topics

  • Alkenes
  • Alkynes
  • Carbon Monoxide
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Dielectric Gases
  • Electrons
  • Ketones
  • Lewis Bases
  • Materials
  • Materials Science
  • Monoxides
  • Organic Chemistry
  • Silicon Compounds
  • Transition Metals

Fields of Study

  • Chemistry

Readers

  • Molecular and Cellular Biochemistry
  • Organic Chemistry
  • Solar Photovoltaics and Thermoelectric Devices.