The Behavior of Microdisk and Microring Electrodes. Mass Transport to the Disk in the Unsteady State: Coupled Chemical Reactions

Abstract

In this work, we discuss the solution of the differential equations in the cylindrical coordinate system for the case of a coupled CE reaction mechanism at a finite disk electrode. We use the properties of discontinuous integrals of Bessel functions to treat the mixed boundary conditions at the electrode surface and the surrounding insulator. The results are compared to previous analyses and we also make comparisons of various estimates of the chronoamperometric response for constant surface concentration conditions.

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Document Details

Document Type
Technical Report
Publication Date
Jul 15, 1988
Accession Number
ADA200422

Entities

People

  • M. Fleischmann
  • Stanley Pons

Organizations

  • University of Utah

Tags

Communities of Interest

  • Energy and Power Technologies
  • Ground and Sea Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Abstracts
  • Bessel Functions
  • Chemical Engineering
  • Chemical Reactions
  • Chemistry
  • Coordinate Systems
  • Differential Equations
  • Electrodes
  • Engineering
  • Equations
  • Integrals
  • Mass Transfer
  • Military Research
  • New York
  • Security
  • Steady State
  • United States

Readers

  • Electrochemical Surface Science
  • Fluid Dynamics.

Technology Areas

  • Microelectronics