Spectroscopic Studies of Fluid/Solid Interfaces

Abstract

This program of research has been to develop spectrosco pic methods for exploring chemical structure and molecular dynamics at interfaces between dielectric solids and liquids or supercritical fluids. The research was carried out using fluorescence and vibrational spectroscopy from probe molecules where spectral and temporal differences in emission, absorption, or scattering provide information about the surface onto which they are absorbed or bound. Studies focused on the interfacial chemistry of silica and derivatized silica surfaces in contact with liquids and dense gases. The spectral response of probe molecules was used to observe differences in the chemical environment at the liquid-solid interface due to the presence of bound or adsorbed molecules.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1988
Accession Number
ADA202436

Entities

People

  • Joel M. Harris

Organizations

  • University of Utah

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Kinetics
  • Chemical Synthesis
  • Chemistry
  • Composite Materials
  • Detection
  • Dynamics
  • Fluids
  • Kinetics
  • Liquid Chromatography
  • Liquids
  • Molecular Dynamics
  • North America
  • Optical Materials
  • Organic Chemistry
  • Physical Chemistry
  • Spectroscopy
  • Universities

Fields of Study

  • Chemistry

Readers

  • Electrochemical Surface Science
  • Quantum Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.