Spectral Identification of Al3Cl10 in 1-Methyl-3-Ethylimidazolium Chloroaluminate Molten Salt

Abstract

The infrared specular reflection of molten 1-methyl-3- ethylimidazolium (MEI) Al3Cl10 is reported. After elimination of vibrational bands due to MEI+, Al2Cl7- and Al2Cl6, the following bands were assigned to Al3Cl10-: 583, 540, 488, 424, 361, 293 and 174/cm. MNDO-MOPAC calculations were carried out and the predicted frequencies and intensities agreed remarkably well with the experimental spectrum. Aluminum chlorides, Imidazoles, Aluminates, Reprints.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1988
Accession Number
ADA203370

Entities

People

  • C. J. Dymek Jr.
  • H. A. Oeye
  • J. S. Wilkes
  • M. A. Einarsrud

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Abstracts
  • Air Force
  • Aluminum
  • Availability
  • Chemistry
  • Chlorides
  • Classification
  • Frequency
  • Frequency Shift
  • Geometry
  • Identification
  • Intensity
  • Pressure Measurement
  • Reflection
  • Security
  • Spectra
  • Specular Reflection

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Systems Analysis and Design