The Microstructural and Phase Characterization of RST A1-Ti-X Alloys

Abstract

Powder Metallurgy A1-4 wt. % Ti and A1-6 wt. % Ti alloys have demonstrated potential for elevated temperature (200-300 C) aircraft applications. These materials derive their excellent strength, ductility, and creep resistance from their fine grain structure, oxide dispersion, and A1 Ti intermetallics. Inert gas atomization and mechanical alloying have been used to produce the binary alloy powders; however, Because of the large solidification range (1200-665 C) large quantities of primary A13 Ti were produced. In this study A1-Ti, A1-TiCe, and A1-Ti-V alloy powders were produced by melt spinning. The alloys were fully characterized in order to assess the effect of composition and processing conditions on microstructure and phase stability. Optical and electron microscopy was used to study the morphology and distribution of second phase disperoids. X-ray diffraction, differential scanning calorimetry (DSC), and selected area electron diffraction (SAD) techniques were used to establish the crystallography of the phases present. The microstructure of the melt spun A1-Ti-X alloys have a higher volume fraction of finely dispersed submicron aluminides than did the previously studied inert gas atomized alloy powders. The major phases identified included A1 (fcc), A13 Ti(14/mmm), and A13 Ti (14/mmm). Keywords: Rapid solidification, Aluminum, Titanium, Aluminum alloys, Vanadumm, Cerium, Titanium alloys.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1988
Accession Number
ADA203734

Entities

People

  • James J. Thompson
  • William E. Frazier

Organizations

  • Naval Air Warfare Center Warminster

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Aircrafts
  • Aluminum Alloys
  • Chemistry
  • Crystal Structure
  • Electron Microscopy
  • Elements
  • Fiber Spinning
  • High Temperature
  • Materials
  • Materials Engineering
  • Materials Processing
  • Mechanical Properties
  • Particle Size
  • Phase Transformations
  • Solid Solutions
  • Titanium
  • Titanium Alloys

Fields of Study

  • Materials science

Readers

  • Powder metallurgy of Titanium alloys.

Technology Areas

  • Microelectronics