Derivative Chemistry of the 1,3,2-Diazaboracyclohexane Ring System. Boron-Nitrogen Polymer Precursors

Abstract

As part of a study of potential synthetic routes to tractable, linear B-N and/or B-N-P polymers, we have prepared a series of new N-silyl, N-boryl, and N-phosphoryl derivatives of the diazaboracyclohexane ring system. The synthesis, structure, dynamic stereochemistry, and some preliminary thermolysis studies of several of these compounds are reported. Aminoborane, Diazaboracyclohexane, Boron, Nitrogen polymer, Iminoborane, Boranes, Hexanes.

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Document Details

Document Type
Technical Report
Publication Date
Jan 26, 1989
Accession Number
ADA204050

Entities

People

  • C. E. Davis
  • G. M. Scheide
  • Parijat Mukherjee
  • R. H. Neilson
  • Souradet Y. Shaw

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  • Texas Christian University

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  • Chemistry

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  • Organic Chemistry