Fuels Combustion Research

Abstract

Studies of near and slightly sooting inverse and normal co-flow diffusion flames determined aromatics as the key intermediates to soot formation. The extent of aromatic formation correlated with the earlier Princeton smoke height test results. The effect of oxygen addition to tightly bound fuels (ethene, ethyne and benzene) in diffusion flames was found to accelerate the pyrolysis and thus the soothing tendency, but not to affect other fuels in the temperature range of soot formation. Flow reactor experiments determined oxidation kinetic results for the mono and dialkylated aromatic components of jet fuels. Succinctly, it was found that the alkyl chains are attached initially and in the case of dialkylated compounds not simultaneously. Mechanisms have been presented. Results on boron slurry droplet combustion were obtained and provided a basis for calculating when droplet disruption would occur. Questions with respect to boron cloud combustion addressed mechanisms of ignition and combustion in the regime of chemical kinetic control.

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Document Details

Document Type
Technical Report
Publication Date
Nov 30, 1988
Accession Number
ADA204161

Entities

People

  • Forman A. Williams
  • Frederick L. Dryer
  • Irvin Glassman

Organizations

  • Princeton University

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies
  • Space

DTIC Thesaurus Topics

  • Abstracts
  • Alkenes
  • Aromatic Hydrocarbons
  • Boiling Point
  • Burning Rate
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Combustion Products
  • Cyclic Hydrocarbons
  • Diffusion
  • Fuels
  • Heat Transfer
  • Hydrocarbon Fuels
  • Ignition
  • Measurement
  • Pyrolysis

Fields of Study

  • Chemistry

Readers

  • Combustion science or combustion engineering.
  • Petroleum Engineering