The Relative Stabilities of Tungsten Hexacarbonyl, Silver Neodecanoate, Some Metal Acetyl- and Hexafluoroacetyl-Acetonates and the Thermal Properties of the Pallidium (2) Acetonates

Abstract

The relative stabilities of silver neodecanoate, tungsten hexacarbonyl, and a series of metal acetyl- and hexafluoroacetyl- acetonates, were determined using differential thermal analysis (DTA) and weight loss analysis. In general, the acetylacetonates decompose in the solid state at relatively low temperatures(100-200 C), with several of them exhibiting appreciable vapor pressures at temperatures below which their decomposition rate is significant. Hexafluoro derivatives of these compounds are, in general, more volatile and decompose at higher temperatures. Chemical reactions.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Feb 03, 1989
Accession Number
ADA204790

Entities

People

  • Arnold Reisman
  • Shelly L. Poston

Organizations

  • North Carolina State University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Barometric Pressure
  • Body Weight
  • Boiling Point
  • Carbonyl Complexes
  • Chemical Engineering
  • Chemical Reactions
  • Chemistry
  • Decomposition
  • Engineering
  • Low Temperature
  • Materials
  • Materials Science
  • Military Research
  • North Carolina
  • Thermal Properties
  • Vapor Pressure
  • X Rays

Readers

  • Analytical Chemistry
  • Control Systems Engineering.
  • Electrochemical Engineering/ Fuel Cell Technologies