Characterization and Cure Monitoring of Structural Adhesives

Abstract

Two potential replacement adhesives for a discontinued commercial adhesive were investigated. The composition and curing behavior of the replacements were compared to the commercial system utilizing a number of analytical techniques. High performance liquid chromatography, size exclusion chromatography, and thermogravimetric analysis were applied to establish the lot-to-lot consistency of the adhesive component composition. The thermal, dynamic mechanical, rheological, and dielectric properties, as a function of cure, were monitored by differential scanning calorimetry, torsional braid analysis, parallel plate rheometry, and microdielectrometry, respectively. Correlations between the various techniques and the state of cure of the adhesive were made. The glass transition temperature of the adhesive was observed to be a very sensitive measure of the state of cure. Keywords: Adhesives, Characterization, Curing, Analytical techniques, Thermal analysis.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1989
Accession Number
ADA206611

Entities

People

  • David A. Dunn
  • Howard H. Wong
  • Stanley E. Wentworth
  • Walter X. Zukas

Tags

Communities of Interest

  • Advanced Electronics
  • Weapons Technologies

DTIC Thesaurus Topics

  • Adhesives
  • Air Force
  • Aluminum
  • Chemistry
  • Composite Materials
  • Detectors
  • Dielectric Properties
  • Engineering
  • Glass
  • Glass Transition Temperature
  • Heat Energy
  • Liquid Chromatography
  • Materials
  • Materials Science
  • Military Research
  • Transition Temperature
  • Transitions

Fields of Study

  • Materials science

Readers

  • Analytical Chemistry
  • Polymer Science and Engineering.
  • Regression Analysis.