Chemical Vapor Deposition of Silicon Carbide Using a Novel Organometallic Precursor

Abstract

Dense silicon carbide films have been prepared by low pressure chemical vapor deposition (LPCVD) using a volatile, heterocyclic, carbosilane precursor. At deposition temperatures between 700 and 800 C, polycrystalline, stoichiometric SiC films have been deposited on single crystal silicon and fused silica substrates. Optical microscopy and SEM analyses indicated formation of a transparent yellow film with a uniform, featureless surface and good adherence to the Si(111) substate. The results of preliminary studies of the nature of the gaseous by-products of the CVD processes and ultrahigh vacuum physisorption and decomposition of the precursor on Si(100) substrates are discussed. Keywords: Organic chemistry, Physical chemistry, Silica, Films, CVD, Silicon carbide, Organometallic precursor.

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Document Details

Document Type
Technical Report
Publication Date
May 15, 1989
Accession Number
ADA208273

Entities

People

  • Bing-xi Sun
  • Corrina Czekaj
  • John Hudson
  • Klaus Lenz
  • Leonard V. Interrante
  • Wei Lee

Organizations

  • Rensselaer Polytechnic Institute

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Ceramic Materials
  • Chemical Analysis
  • Chemical Compounds
  • Chemical Vapor Deposition
  • Chemistry
  • Electron Microscopes
  • Electron Microscopy
  • Materials
  • Materials Engineering
  • Measurement
  • Microscopy
  • New York
  • Organic Chemistry
  • Physical Chemistry
  • Silicon Carbide
  • United States
  • Vapor Deposition

Readers

  • Thin Film Deposition Science.