Triplet Extinction Coefficients of Some Laser Dyes. 1

Abstract

For flashlamp pumped dye lasers, the negative effect of triplet state losses on laser action efficiency is well known. Oscilloscope traces of laser pulses showed that laser action diminishes much sooner than the flashlamp excitation pulse. This effect was attributed to the buildup of triplet-state dye molecules during the excitation from the flashlamp pulse. We measured the triplet extinction coefficients epsilon(T) over the laser action spectral region of Rhodamine 6G; Rhodamine B; Rhodamine 110; Fluorol-7GA; Coumarin 540A; Coumarin 522; Coumarin 1; Coumarin 120; 4,4'-diphenyl stilbene; and 2,7-bis(4-methoxy-phenyl)-9,9-dipropylfluorene. We employed the different lines from an argon ion cw laser for excitation. McClure's method was used to obtain the triplet extinction coefficients Epsilon(T). The method requires the measurement of triplet optical densities OD(T) as a function of different cw laser excitation intensities (powers) I(ex). The importance of triplet-state losses on dye laser efficiency is reviewed. The laser action properties of the laser dyes we studied are briefly discussed as they relate to the measured epsilon=(T) values. Keywords: Tunable lasers, Optical communications, Reprints.

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Document Details

Document Type
Technical Report
Publication Date
Mar 01, 1989
Accession Number
ADA208291

Entities

People

  • Daniel J. Golich
  • Theodoren G. Pavlopoulos

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Dye Lasers
  • Dyes
  • Equations
  • Errors
  • Fluorescence
  • Ion Lasers
  • Laser Beams
  • Laser Dyes
  • Laser Pulses
  • Lasers
  • Light (Electromagnetic Radiation)
  • Light Sources
  • Liquid Dye Lasers
  • Measurement
  • New York
  • Organic Compounds
  • Stilbenes

Fields of Study

  • Physics

Readers

  • Chemistry (specifically Chemical Fluorescence)
  • Optical Physics and Photonics.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers