Magnetic and Electrical Properties of Sandwich-Like Lanthanide Phthalocyanines
Abstract
Rare earth phthalocyanine sandwich compounds and their iodine analogues have been synthesized. Single crystals were obtained by electrochemical means, and magnetic susceptibility measurements on the polycrystalline samples follow the Curie Weiss law. Room temperature and 77 K EPR spectra at X band for undoped lutetium phthalocyanine indicate the presence of a free radical phthalocyanine unit. Doped complexes also show a narrow signal with a g value of 2.00. Keywords: Electrical conductivity, Magnetic susceptibility, Lutetium, Phthalocyanines, Electron paramagnetic resonance, Semiconductors.
Document Details
- Document Type
- Technical Report
- Publication Date
- May 08, 1989
- Accession Number
- ADA208411
Entities
People
- Juan Padilla
- William E. Hatfield
Organizations
- University of North Carolina at Chapel Hill