Ultrathin Polymer Films for Microlithography

Abstract

Ultrathin (14 - 22 nm) poly(methacrylate) (PMMA) films prepared by both spin casting and Langmuir-Blodgett (LB) techniques and novolac films prepared by spin casting have been explored as high-resolution electron beam resists. One-eighth micron lines-and-spaces patterns have been achieved by using a Perkin Elmer MEBES I pattern generation system as the exposure tool, and the definition of 45 nm features has recently been achieved by using a high resolution electron beam lithography system. The etch resistance of such films is sufficiently good to allow patterning of a chromium film suitable for photomask production. The most surprising result has been that the pinhole densities in 14.3 nm LB PMMA film and 22 nm spin-cast novolac films are only a few per centimeters squared, considerably less than the density in spin-cast PMMA films of comparable thickness. Reprints.

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Document Details

Document Type
Technical Report
Publication Date
May 30, 1989
Accession Number
ADA208982

Entities

People

  • C. C. Fu
  • C. W. Frank
  • David R. Allee
  • P. Maccagno
  • S. W. Kuan

Organizations

  • Stanford University

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Engineering
  • Chemical Synthesis
  • Chemistry
  • Electrical Engineering
  • Electron Beam Lithography
  • Electron Beams
  • Electron Microscopes
  • Electron Microscopy
  • Engineering
  • Fatty Acids
  • Films
  • High Resolution
  • Lithography
  • Measurement
  • Microscopes
  • Military Research
  • Polymeric Films

Readers

  • Nanofabrication and Microfabrication.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Directed Energy - Pulsed-Laser Deposition
  • Microelectronics
  • Microelectronics - Graphene
  • Space