Modelling the In Situ Infrared Reflection-Absorption Spectra of the Diffuse Layer

Abstract

Using a stratified medium model for the electrochemical interface and Gouy-Chapman-Stern theory of the double layer, a method to model infrared reflection-absorption spectra of the diffuse layer is developed. This method is applied to spectra obtained in the double layer region for aprotic, organic electrolytes on gold electrodes. Keywords: Infrared spectroscopy; Raman spectroscopy; Electrode/electrolyte interface; Electrochemistry.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1989
Accession Number
ADA209347

Entities

People

  • P. W. Faguyr
  • S. Mccullough
  • William Ronald Fawcett

Organizations

  • University of California, Davis

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Absorption
  • Absorption Spectra
  • Chemistry
  • Electrochemistry
  • Electrodes
  • Electrolytes
  • Infrared Spectroscopy
  • Military Research
  • New York
  • Optical Properties
  • Raman Spectroscopy
  • Reflection
  • Spectra
  • Spectroscopy
  • United States
  • United States Government

Readers

  • Computational Modeling and Simulation
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Spectroscopy.