The Synthesis and Structure of Novel Antimony Thiametallacycles
Abstract
Recently a dramatic resurgence of interest in the organometallic chemistry of the main group elements has occurred. To a large degree this renewed activity derives from the utility of main group compounds in fields such as ceramics, electronic and thermochromic materials, and marine antifouling compounds. The development of general, efficient synthetic methods for the preparation of hitherto inaccessible main group organometallics should greatly enhance progress in many of these fields. In this communication, we report the preparation and characterization of a new class of main group metallacycle, 4, 5-didehydro-2-thiastibolanes, via a transmetallation from zirconium. Chemical synthesis, Organic chemistry.
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 01, 1989
- Accession Number
- ADA210888
Entities
People
- Richard A. Fisher
- Stephen L. Buchwald
- William M. Davis
Organizations
- Massachusetts Institute of Technology