Effect of Annealing Conditions on the Structural and Superconducting Properties of Y-Ba-Cu-O Films

Abstract

The effect of various annealing treatments on ion beam sputter- deposited Y1Ba2CuyO(7-x)(y=3 and 5) amorphous thin films has been studied using scanning electron microscopy (SEM), X-ray diffraction and dc resistivity measurements. SEM analysis showed that the morphology of the films were clearly divided into three categories: an equiaxial grain structure, a well-oriented grid-like microstructure and a textured platelet structure. The equiaxial grain structure (random orientation according to X-ray diffraction measurements) was obtained when the film was annealed at slow heating and cooling rates in an oxygen atomosphere. The grid-like microstructure (b/c-axes oriented normal to the plane) was obtained in Cu-rich composition (y=5) by rapid thermal annealing. A textured platelet microstructure (c-axis oriented normal to the plane) was obtained using slow heating rates and by carefully controlling the gas environment at the temperature region near the orthorhombic-tetragonal transition. Thus, we have demonstrated the ability to control the morphology and orientation of the film by varying the annealing process.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1989
Accession Number
ADA211308

Entities

People

  • Carmine Vittoria
  • Daniel F. Ryder Jr.
  • Jae Ryu
  • James V. Marzik
  • Yizhou Huang

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Advanced Materials
  • Air Force
  • Diffraction
  • Electron Microscopy
  • Engineering
  • Films
  • Ion Beams
  • Materials
  • Materials Science
  • Measurement
  • Microstructure
  • Military Research
  • Thin Films
  • Transition Temperature
  • Transitions
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene