Electron Attachment and Molecular Fragmentation in Laser-Excited Plasmas

Abstract

Production of O- from thermal electrons has been identified during the laser excitation of NO. O- is produced during excitation near 226 nm, corresponding to absorption in the (0,0) band of the A-X band system of NO. Electrons with energy limited to <0.5 eV completely suppress the endothermic production of O- from NO(X2II). Dissociative attachment occurs from the A2 + electronic state of NO and produces both O- and N in their ground electronic states. This is the first reported case of dissociative attachment of electrons to an optically prepared excited electronic state. Keywords: Multiphoton ionization; Capture; Attachment; Detection; Ion; Nitric oxide.

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Document Details

Document Type
Technical Report
Publication Date
Aug 10, 1989
Accession Number
ADA212098

Entities

People

  • J. L. Hardwick
  • J. T. Moseley

Organizations

  • University of Oregon

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Absorption
  • Charged Particles
  • Detection
  • Dye Lasers
  • Electron Energy
  • Electron Guns
  • Electronic States
  • Electrons
  • Emission
  • Emission Spectra
  • Energy
  • Energy Transfer
  • Lasers
  • Liquid Dye Lasers
  • Molecules
  • Small Molecules
  • Spectra

Fields of Study

  • Physics

Readers

  • Pulsed Power and Plasma Physics.
  • Quantum Chemistry
  • Software Engineering

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Microelectronics