Growth and Characterization of Zinc Sulfide Films by Conversion of Zinc Oxide Films with H2S

Abstract

Zinc sulfide is an IR window material and a transparent semiconductor with a large direct band gap. It also possesses piezoelectric, photoconductive and electroluminescent properties. Thin films of zinc sulfide can be utilized for infrared antireflection coatings, light-emitting diodes (LEDs), electroluminescent (EL) displays, multilayer dielectric filters, optical phase modulation and light guiding in integrated optics. In recent years, there has been a large amount of effort directed at the growth of high quality films of ZnS. Various fabrication techniques have been employed, such as ion beam epitaxy sputtering atomic layer epitaxy (ALE), molecular beam (MBE), metal-organic chemical vapor deposition and spray pyrolysis. Zinc sulfide films were prepared by conversion of zinc oxide films in the presence of hydrogen sulfide. The films which contained both the hexagonal and cubic forms of zinc sulfide were shown to be uniform and gave a measured band gap of 3.65 eV. (KT)

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Document Details

Document Type
Technical Report
Publication Date
Sep 26, 1989
Accession Number
ADA213345

Entities

People

  • Aaron Wold
  • J. Baglio
  • Kirby Dwight
  • P. Wu
  • Y. M. Gao

Organizations

  • Brown University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Band Gaps
  • Chemistry
  • Classification
  • Compound Semiconductors
  • Diffraction
  • Diffraction Analysis
  • Electron Microscopes
  • Electron Microscopy
  • Films
  • Infrared Spectra
  • Materials
  • Military Research
  • Oxide Films
  • Scanning Electron Microscopy
  • Spectra
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Materials science

Readers

  • Optical Physics and Photonics.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene