A Novel Heat Resistant Blend Produced by Compositional Quenching: A thermoplastic Polyimide Impact Modified with a Fluoroelastomer

Abstract

The polymers used in this work are Ultem, a thermoplastic polyimide produced by General Electric, and Viton A, a fluoroelastomer made by Dupont. Both the polymer and rubber were chosen for this study because of their excellent thermal stability. Ultem is a heat and chemical resistant polymer that suffers from poor impact strength. The addition of a dispersed rubber phase to Ultem significantly reduces this problem. Compositional quenching is a process in which a single-phase solution consisting of two (or more) polymers dissolved in a common solvent is heated and then flashed in a vacuum chamber. Rapid devolatilization of the solvent results leaving behind a two-phase polymer blend in which the minor component is microdispersed within the major component through the action of spinodal decomposition. Through the process of compositional quenching, Ultem-Viton blends were produced that contained relatively uniform-sized, spherical Viton particles approximately one-half micron in diameter.

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Document Details

Document Type
Technical Report
Publication Date
Aug 15, 1989
Accession Number
ADA213724

Entities

People

  • E. B. Nauman
  • John S. Furno

Organizations

  • Rensselaer Polytechnic Institute

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Biomedical And Dental Materials
  • Crack Tips
  • High Temperature
  • Impact Strength
  • Materials
  • Materials Processing
  • Materials Science
  • Mechanical Properties
  • Mechanics
  • Particle Size
  • Polymer Degradation
  • Resins
  • Stress Strain Relations
  • Stresses
  • Thermal Stability
  • Thermoplastic Resins
  • Yield Strength

Fields of Study

  • Materials science

Readers

  • Polymer Science and Engineering.
  • Powder metallurgy of Titanium alloys.