Dispersion Strengthening of High Temperature Niobium Alloys

Abstract

Niobium base alloys are very attractive as high temperature materials for advanced gas turbine applications. After many conventional metallurgical approaches, a high temperature creep resistant alloy has yet to be identified which will replace nickel base superalloys. The best chance for obtaining high temperature creep resistance in these alloys is through dispersion strengthening with a stable precipitate that is introduced through rapid solidification. This would result in a very fine dispersion of nonshearable precipitates that would not coarsen upon long term exposure at temperatures in excess of 1200 C. A study has been conducted here to identify such a stable dispersion, fabricate alloys through solidification approach and characterize the coarsening of the resulting precipitates. A thermodynamic argument is presented to select candidate dispersions for evaluation. Arc melted and splat quenched alloys were fabricated and evaluated through micro-hardness measurements. An indirect assessment of particle stability is introduced which resulted in a coarsening parameter determined for each candidate precipitate at 1400 C. Microscopic examination of the more stable alloys were made via optical and thin foil TEM analyses. Tensile and strain-rate sensitivity tests were run on these alloys at 1400 C. Niobium, Dispersion strengthening, High temperature strength, Particle coarsening, Refractory metals, Niobium alloys.

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Document Details

Document Type
Technical Report
Publication Date
Jul 31, 1989
Accession Number
ADA213829

Entities

People

  • A. F. Giamei
  • D. B. Snow
  • D. L. Anton
  • L. H. Favrow

Organizations

  • United Technologies Corporation

Tags

Communities of Interest

  • Air Platforms

DTIC Thesaurus Topics

  • Age Hardening
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Electron Microscopy
  • Grain Boundaries
  • Hardening
  • Hardness
  • Materials
  • Measurement
  • Mechanical Working
  • Refractory Metals
  • Solid Solutions
  • Stress Strain Relations
  • Stresses
  • Tensile Strength
  • Transition Temperature

Fields of Study

  • Materials science

Readers

  • Powder metallurgy of Titanium alloys.