Effect of Reduced Atmospheric Pressure on the Performance Characteristics of Pyrotechnic Compositions Containing Aluminum

Abstract

A study of aluminum containing compositions shows that the burning time is greatly increased at simulated high altitude and reduced pressure. Since compositions using the same oxidants but using magnesium as the fuel are not similarly affected, it appears that the use of aluminum is definitely the cause of the increase. Removal or disruption of the oxide coating on the aluminum does not correct the problem. Use of air, argon, helium, or oxygen as the atmospheric gas shows that the problem occurs at or near the burning surface not in the atmosphere. Use of the different fuels demonstrates that the presence or absence of a protective oxide coating does not have an effect; however, the burning time is increased for compositions with high boiling fuels and relatively unaffected for those with low boiling fuels. Since the temperature of reaction is higher than the boiling point for low boiling fuels and lower for high boiling ones, the increase is caused by removal of heat from the surface by increased vaporization of high boiling fuels at low pressure. Keywords: Flame temperature; Burning rate; Luminous output.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1989
Accession Number
ADA214473

Entities

People

  • Clement Campbell
  • Francis R. Taylor
  • Patricia L. Farnell

Organizations

  • United States Army Armament Research, Development and Engineering Center

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Alloys
  • Altitude
  • Aluminum
  • Atmospheres
  • Barometric Pressure
  • Boiling Point
  • Burning Rate
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Differential Thermal Analysis
  • Heat Energy
  • High Altitude
  • Metals
  • Physical Properties
  • Thermal Analysis
  • Thermodynamics

Fields of Study

  • Environmental science

Readers

  • Combustion and Flow Dynamics.
  • Rocket Propulsion.
  • Surface Engineering/Surface Coating Technology.