An Electrochemical and Spectroscopic Study of Electrode Processes

Abstract

Research on the chloroaluminate melt, methyl-ethyl-imidazolium chloride-aluminum chloride has been conducted to elucidate the structural properties of the melt. The melt was studied by obtaining its fluorescence spectra, NMR spectra and its conductance properties. In addition, ab-initio calculations (Extended Huckel M.O.) on the dichloro-hydrogen species were made. In other solution studies, proton NMR, infrared and Raman spectroscopic studies of the lithium-water interactions in acetonitrile were continued. The hydration number for lithium ion (four and the oxygen symmetry, Td, were determined. A gas chromatographic study of the reactivity of lithium with acetonitrile was conducted.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1989
Accession Number
ADA217261

Entities

People

  • Robert G. Keil

Organizations

  • University of Dayton

Tags

DTIC Thesaurus Topics

  • Air Force
  • Chemical Reactions
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Electron Density
  • Infrared Spectra
  • Liquid Chromatography
  • Magnetic Resonance
  • Materials
  • Nitriles
  • Nuclear Magnetic Resonance
  • Perchlorates
  • Physical Properties
  • Plastic Explosives
  • Spectra
  • Spectroscopy

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Quantum Chemistry