Chemical and Electrochemical Studies in Ionic Liquids

Abstract

Chemical and electrochemical studies were carried out in ambient temperature chloroaluminate molten salts composed of aluminum chloride and 1-ethyl-3-methylimidazolium chloride. Simultaneous electrochemical in EPR work was performed on polypyrrole and polyfluorene in the molten salts. The chemistry and electrochemistry of a number of solutes, benzoquinone, several molybdenum dimers, and ferro/ferricyanide, were examined. Oxygen 17 NMR spectroscopy was employed to assess the behavior of oxide in the molten salts. Gutmann donor-acceptor numbers were obtained making use of electrochemical and NMR, Phosphorus 31, measurements. Ionic liquids, Ambient temperature molten salts, Electrochemistry, Chloroaluminates.

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Document Details

Document Type
Technical Report
Publication Date
Jan 12, 1990
Accession Number
ADA217742

Entities

People

  • Robert A. Osteryoung

Organizations

  • University at Buffalo

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Analytical Chemistry
  • Chemical Compounds
  • Chemical Synthesis
  • Chemistry
  • Conductive Polymers
  • Cyanides
  • Electrochemistry
  • Hydrogen
  • Inorganic Chemistry
  • Ionic Liquids
  • Liquids
  • Measurement
  • Metals
  • Organic Chemistry
  • Physical Chemistry
  • Quinones

Fields of Study

  • Chemistry
  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Polymer Science and Technology