Growth, Characterization and Device Development in Monocrystalline Diamond Films

Abstract

Two chemical vapor deposition (CVD) systems (hot filament and microwave plasma) and a multitechnique analysis system have been designed, constructed and characterized. The effects of surface steps, substrate material and substrate/filament bias have been examined. Diamond films from outside sources have been analyzed by a variety of techniques. Most notably, numerous defects, especially (111) twins, have been identified by TEM and are similar to those found in natural diamond. Certain diamond particles were in a twinned epitaxial relationship with the Silicon substrate. It has also been found that a thin Silicon carbide layer forms immediately (i.e. <5 min) upon exposure to the Methane + Hydrogen plasma, followed by the slow formation of the diamond crystallites. Large-Signal, nonlinear device models for both microwave diamond power MESFETs and mm-wave diamond IMPATT diodes have been developed. Diamond power MESFETs operating in X-band are found to be capable of producing approximately 25 W/unit gate width of RF power with a power-added efficiency of greater than 40%. A diamond IMPATT oscillator should produce about 2 W RF power with an efficiency of 10% at 100 GHz. Keywords: Thin films.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1990
Accession Number
ADA218211

Entities

People

  • J. T. Glass
  • K. J. Bachmann
  • R. J. Trew
  • Robert F Davis
  • Robert J. Nemanich

Organizations

  • North Carolina State University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Engineering
  • Chemistry
  • Coatings
  • Crystal Structure
  • Crystals
  • Mass Spectrometry
  • Materials
  • Materials Science
  • Measurement
  • Semiconductor Devices
  • Semiconductors
  • Silicon Carbide
  • Solid State Physics
  • Spectra
  • Spectrometry
  • Three Dimensional
  • Two Dimensional

Readers

  • Electronics Engineering
  • Thin Film Deposition Science.