Structure of Monopropellant Spray Flames at Elevated Pressures

Abstract

The combustion properties of HAN-based monopropellants (LGP1845 and 1846) were studied, considering: liquid surface properties and conditions required for the thermodynamic critical point to be reached, drop combustion properties in combustion gas environments at pressures of 0.2-7.0 MPa, and pressure-atomized spray combustion properties in combustion gas environments at pressures of 3-9 MPa. Computations of liquid surface properties in flame environments indicated unusually high liquid surface temperatures, ca. 1000K, and critical combustion pressures, ca. 250 MPa, since these propellants have thermodynamic properties similar to molten salts. Drop burning was dominated by subsurface reaction leading to bubble formation and microexplosions which mechanically removed liquid, at low pressures (less that 2.1 MPa); and conventional heterogeneous combustion from the surface at high pressures (greater than 2.1 MPa). The resulting apparent burning rates were relatively independent of pressure and were large, ca. 10 mm/s, which is consistent with earlier strand burning rate measurements of jelled propellants at pressures greater than 10 MPa by McBratney (1980, 1981). Measurements of drop size distributions, liquid flow rates, and liquid mass fluxes in combusting sprays were consistent with the individual drop burning rate measurements and exhibited strong effects of separated flow. Keywords: Spray combustion; Liquid propellants; Monopropellant combustion.

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Document Details

Document Type
Technical Report
Publication Date
Jan 15, 1990
Accession Number
ADA218676

Entities

People

  • Gerard M. Faeth
  • L.-k. Tseng
  • M. E. Kounalakis
  • T.-w. Lee

Organizations

  • University of Michigan

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Boundary Layer
  • Burning Rate
  • Cameras
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Combustion
  • Computational Fluid Dynamics
  • Computer Programs
  • Energy Transfer
  • Equations Of State
  • Flow Visualization
  • Fluid Flow
  • High Pressure
  • Rocket Oxidizers
  • Surface Properties
  • Turbulent Mixing

Fields of Study

  • Physics

Readers

  • Combustion and Flow Dynamics.
  • Rocket Propulsion.