Morphology Changes Due to Oxidative Treatment of Glassy Carbon Electrodes and Its Applications

Abstract

Oxidative (anodic) treatment of glassy carbon(GC) in aqueous alkaline media was found to cause the formation of a unique mesa morphology. Injection of some species (perhaps OH(-)) below the surface with attendant volume change was suspected to be the cause for the peculiar morphological change. The present paper reports the mechanism of the mesa formation and its application to enhance the catalytic activity for electropolymerization of conducting polymers and the double-layer capacitance of the resulting polypyrrole/GC film. Keyword: Electrochemistry/catalysts.

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Document Details

Document Type
Technical Report
Publication Date
Jan 25, 1990
Accession Number
ADA219425

Entities

People

  • Ali Firouzi
  • Katsuhiko Naoi
  • William H. Smyrl’

Organizations

  • University of Minnesota

Tags

DTIC Thesaurus Topics

  • Abstracts
  • Conductive Polymers
  • Corrosion
  • Diameters
  • Electrochemical Reactions
  • Electrochemistry
  • Electrodes
  • Electron Microscopy
  • Elements
  • Films
  • Materials
  • Minnesota
  • Photoelectrochemical Cells
  • Polymers
  • Polypyrroles
  • Scanning Electron Microscopy
  • Thin Films

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Polymer Science and Technology
  • Systems Analysis and Design