Synthesis and Anionic Ring Opening Polymerization of 1-Germa-1,1- Dimethy1(3,4,c)thienocyclopentane

Abstract

1-Germa-1, 1-dimethyl(3,4,C)thenocyclopentane (I) has been prepared from 3-germa-3,3-dimethyl-7-thiabicyclo(3,3,0)oct-1-ene (II) by oxidation with dichlorodicyanoguinone (DDQ). Treatment of I with a catalytic amount of n- butyllithium and hexamethylphosphoramide in tetrahydrafuran yields poly (1- germa-1,1-dimethyl(3,4,C)thienopentane) (III). 1-Germa-1, 1-dimethyl(3.4.C) thenocyclopentane, Anionic ring opening polymerization, TGA, Organic chemistry.

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Document Details

Document Type
Technical Report
Publication Date
May 09, 1990
Accession Number
ADA221606

Entities

People

  • C. Laurent
  • Pierre Mazerolles
  • Stephen Q. Zhou
  • William P. Weber

Organizations

  • University of Southern California

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  • Advanced Electronics

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  • Abstracts
  • Alkanes
  • California
  • Chemical Synthesis
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  • Glass Transition Temperature
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  • Materials Science
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  • Polymers
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  • Spectra
  • Spectroscopy
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Fields of Study

  • Chemistry

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