Experimental Evaluation of the Synthetic Solid Electrolyte Interface (SSEI) Concept for the Primary Ca-SOCl2 Battery System

Abstract

The Ca-SOCl(2) primary battery system has an excellent safety profile when subjected to a variety of abuse test conditions. Furthermore its theoretical energy density qualifies it for a variety of demanding Army and other DOD applications. Recently, significant improvements have been reported in the low temperature performance and the cathode capacity obtainable in this system. One major remaining flaw, however, is the corrosion of the Ca anode during storage at elevated temperature. Efforts to modify the electrolyte or provide a protective coating for the anode have had only limited success. The purpose of the present research has been to apply the concept of a synthetic solid electrolyte interface (SSEI) to overcome the problem of Ca corrosion in Ca-SOCl(2) primary cells.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1988
Accession Number
ADA221872

Entities

People

  • J. P. De Neufville

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Calcium Hydroxide
  • Chemical Analysis
  • Chemistry
  • Coatings
  • Composite Materials
  • Corrosion
  • Corrosion Inhibition
  • Electron Microscopes
  • Electron Microscopy
  • Low Temperature
  • Metals
  • Physics Laboratories
  • Protective Coatings
  • Scanning Electron Microscopes
  • Scanning Electron Microscopy
  • Surface Chemistry
  • X Rays

Fields of Study

  • Materials science

Readers

  • Battery Technology and Engineering
  • Surface Coatings Technology.
  • Systems Analysis and Design