Passive Mechanisms of Surfaces Produced by Ion Beam Mixing and Ion Implantation

Abstract

The corrosion behavior of Mo-Al, Cr-Al and Cr-Mo-Al surface alloys produced by ion implantation and ion beam mixing was examined in deaerated, 0.1M NaC1. The polarization behavior of the ion implanted samples was similar to that of Al and the pitting potentials of the ion implanted samples were 115 to 155 mV higher than that of Al. From the standpoint of the Ph sub pzc model this behavior would be explained by the presence of the implanted cations in the stable oxide lattice. There was incomplete mixing of the coating and substrate for the ion beam mixed samples, and the mixed elements remained almost entirely in the metallic state so that the desired mixed oxide films were not formed. Ion beam mixing did impart additional stability compared to as-deposited samples since the mixing process produced more compact coatings.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1990
Accession Number
ADA222432

Entities

People

  • E. Mccafferty
  • G. K. Hubler
  • P. M. Natishan

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Adsorption
  • Aluminum Oxides
  • Anodic Polarization
  • Chemical Compounds
  • Chemistry
  • Coatings
  • Elements
  • Films
  • Implantation
  • Ion Beams
  • Ion Implantation
  • Materials
  • Materials Science
  • Metals
  • Oxide Films
  • Polarization
  • Resistance

Fields of Study

  • Materials science

Readers

  • Materials Science and Engineering.
  • Powder metallurgy of Titanium alloys.
  • Thin Film Deposition Science.