Specific Radioisotopic Assay for Cholinesterase

Abstract

The radiometric method (I) for measuring ChE activity (Siakotos et al., Biochem. Med. 3, 1, 1969) was modified to preclude the use of p-dioxane, a hazardous material. The modified procedure (II) uses 0.4 N perchloric acid (PCA) , instead of p-dioxane, to denature the ChE and stop hydrolysis of 14C- acetylcholine (ACh). The unreacted substrate (ACh) is removed by cationic exchange resin suspended in water. The supernatant (acidic water solution) containing the product of hydrolysis, 14C-acetic acid, is mixed with nonhazardous scintillation cocktail and counted. The incubation mixture (37 degrees C) for II is similar to I and is composed of 0.1 ml of buffer-salt solution (pH 7.8), 0.1 ml of guinea pig whole blood (WB)-water suspension and 0. 1 ml of 3mM ACh solution. Keywords: Acetylcholinesterase; Acetylcholine; Radiometric ChE assay; Physostigmine; Irreversible ChE inhibitors; Titrametric ChE assay.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1990
Accession Number
ADA224444

Entities

People

  • Brian G. Talbot
  • Dana R. Anderson
  • Larrel W. Harris
  • Willard J. Lennox

Organizations

  • United States Army Medical Research Institute of Chemical Defense

Tags

DTIC Thesaurus Topics

  • Acetic Acid
  • Acetylcholinesterases
  • Animals
  • Biological Sciences
  • Blood
  • Enzymes
  • Erythrocytes
  • Hazardous Materials
  • Hydrolysis
  • Inhibitors
  • Laboratory Animals
  • Materials
  • Measurement
  • Military Research
  • Perchloric Acid
  • Rodents
  • Scintillation

Fields of Study

  • Chemistry

Readers

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