Synthesis and Characterization of (Me3Si)2AsCH2RCH2As(SiMe3)2 (R = CH2, SiMe2) and Ph2GaCl(Ph)2Ga(Me3Si)As(CH2)3As(SiMe3)Ga(Ph)2ClGaPh2

Abstract

The synthesis and characterization of (Me3Si)2AsCH2RCH2As(SiMe3)2 R=CH2 (1), SiMe2 (2) is described. Compound 1 reacts with four equivalents of Ph2GaCl to Ph2(GaCl(Ph)2Ga(Me3Si)As)(CH2)3(As(SiMe3)Ga(Ph)2ClGa)Ph2 (3), whose structure was deduced by use of 1H and 13C(1H) NMR spectroscopy. Keywords: Gallium arsenic; Bisarsine; Synthesis.

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Document Details

Document Type
Technical Report
Publication Date
Jul 28, 1990
Accession Number
ADA224945

Entities

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  • C. C. Pitt
  • J. W. Pasterczyk
  • R. L. Wells
  • W. K. Holley

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  • Duke University

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