Bis(Phthalocyaninato) Lanthanide Sandwich Compounds Exhibiting Mixed Valence Ligands
Abstract
Bis(phthalocyaninato) lanthanide sandwich compounds have been synthesized for ytterbium and thulium. Low temperature magnetic susceptibility data suggest a strong antiferromagnetic interaction between the lanthanide f- electrons and the phythalocyaninato ligand radical electron. Keywords: Lanthanide; Ytterbium; Thulium; Phthalocyanine; Magnetic susceptibility; Electron paramagnetic resonance; Electronic spectroscopy; Intervalence charge transfer.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 13, 1990
- Accession Number
- ADA225004
Entities
People
- Kathleen L. Trojan
- Keith D. Kepler
- Martin L. Kirk
- William E. Hatfield
Organizations
- University of North Carolina at Chapel Hill