Feasibility of a Super High Energy Density Battery of the Li/Br/F3 Electrochemical System

Abstract

Feasibility studies on the practical aspects of developing a lithium/ bromine trifluoride battery have been studied. Efforts directed toward identifying materials for porous electrode separators, glasses for insulated electrical feed-throughs, and metals for lid, case and current collector fabrication via electrochemical testing techniques have resulted in a list of materials suitable for these applications. Prototype cells utilizing a spirally wound electrode configuration have been constructed and discharged. The use of lithium salts as an electrolyte additive has been explored, and has shown a positive effect on discharge performance. Through the use of currently available technology, however, the lithium/bromine trifluoride couple has not delivered energy density comparable to other high energy density lithium systems. This investigation has revealed that practical Li/BrF3 cell development will require further extensive fundamental electrochemical research.

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Document Details

Document Type
Technical Report
Publication Date
Aug 16, 1990
Accession Number
ADA225508

Entities

People

  • Christine A. Frysz
  • Michael F. Pyszczek
  • Steven J. Ebel

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Cells
  • Cellular Structures
  • Current Density
  • Electrochemical Cells
  • Electrodes
  • Electron Microscopy
  • Energy
  • Fabrication
  • Failure Mode And Effect Analysis
  • Films
  • Fluoropolymers
  • High Energy
  • Materials
  • Metals
  • Scanning Electron Microscopy
  • Surface Properties
  • Tensile Strength

Fields of Study

  • Materials science

Readers

  • Battery Technology and Engineering
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Systems Analysis and Design

Technology Areas

  • Microelectronics