Synthesis, Structure and Pyrolysis of Organoaluminum Amides Derived from the Reaction of Trialkylaluminum Compounds with Ethylenediamine in a 3:2 Ration

Abstract

The reactions of triethylaluminum and trimethylaluminum with ethylenediamine (en) in a 3:2 ratio have been studied. Heating of the initially formed 2R3Al:en and R3 Al:en adduct mixture results in the formation of RA1((HN(CH2)2NH)A1R2)2 (R = CH3 and C2H5). The structures and formation mechanisms of these two compounds, as well as their pyrolysis reactions, have been studied with H, C, A1 NMR, FTIR, MS, GC, DSC, and TGA. The methyl derivative was characterized by a single crystal X-ray diffraction analysis. (jes)

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1990
Accession Number
ADA225758

Entities

People

  • Daekeun Kwon
  • Fook S. Tham
  • Leonard V. Interrante
  • Rudy Kullnig
  • Zhiping Jiang

Organizations

  • Rensselaer Polytechnic Institute

Tags

Communities of Interest

  • C4I

DTIC Thesaurus Topics

  • Air Force
  • Alkanes
  • Aluminum Nitrides
  • Body Weight
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Diffraction
  • Diffraction Analysis
  • Inorganic Chemistry
  • Materials
  • Molecular Structure
  • Nitrogen Compounds
  • Organic Chemistry
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry