Diamond Synthesis in a 50kW Inductively Coupled Atmospheric Pressure Plasma Torch

Abstract

Polycrystalline diamond coatings have been deposited on metal substrates using a 50 kW atmospheric pressure inductively coupled plasma torch. The argon-hydrogen-methane plasma generated has a free stream active area of 35 sq. cm. and a temperature of approximately 5000 K. Growth rates obtained for a highly diluted plasma are of the order of 10 um/hour. In this work, a flat plate boundary layer flow reactor is used to generate diamond growth at a surface in a well understood fluid dynamic situation. The growth morphology is found to vary significantly with reactor processing conditions and location downstream of the leading edge. Scanning electron microscopy indicates that well faceted crystals are obtained with growth along the 100 and 111 planes. Nearly continuous films are also formed and found to be lower quality. The results are compared to the predictions of a two-dimensional boundary layer model of the reacting flow environment. Measured and predicted growth rates show good agreement.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1990
Accession Number
ADA227563

Entities

People

  • C. H. Kruger
  • D. G. Goodwin
  • M. A. Cappelli
  • T. G. Owano

Organizations

  • Stanford University

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Barometric Pressure
  • Boundary Layer
  • Boundary Layer Flow
  • Chemical Equilibrium
  • Chemical Reaction Properties
  • Chemical Reactions
  • Chemical Vapor Deposition
  • Chemistry
  • Electron Density
  • Electrons
  • Engineering
  • Fluid Dynamics
  • Free Stream
  • Leading Edges
  • Measurement
  • Surface Reactions
  • Temperature Gradients

Fields of Study

  • Physics

Readers

  • Materials Science and Engineering.
  • Plasma Physics.
  • Thin Film Deposition Science.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene