Enantiomeric Recognition of Organic Ammonium Salts by Chiral Pyridino- 18-Crown-6 Ligands: A Short Review
Abstract
A short review of enantiomeric recognition of chiral organic ammonium salts by chiral pyridino-18-crown-6 ligands is presented. Topics included preparation of chiral macrocycles and details of enantiomeric recognition as determined by 1H NMR and calorimetry techniques. The chiral pyridino-18-crown-6 ligands containing two tert-butyl or two phenyl substituents on chiral macroring carbon atoms exhibited the highest recognition for the enantiomers of ALPHA, (1- NAPHTHYL)ETHYLammonium perchlorate of any chiral pyridino-18-crown-6 ligands studied. (JS)
Document Details
- Document Type
- Technical Report
- Publication Date
- Oct 24, 1990
- Accession Number
- ADA228546
Entities
People
- C. W. Mcdaniel
- C. Y. Zhu
- F. Huszthy
- J. S. Bradshaw
- M. Oue
Organizations
- Brigham Young University