Molecular Mechanism of Voltage-Dependent Ion Channels

Abstract

The focus of this research is the interaction of a molecule at the lipid/water interface of a membrane with the external electric field, using peptaibols and the S4 segment of the sodium channel as model systems. Experiments are underway to assess the role of the molecular dipole in sensing the imposed molecular field; the role of alpha helix-310-helix transitions in responding to the imposed molecular field as the transduction mechanism; and the role of the channel mouth in determining the ion selectivity associated with channel opening. Ac-(Lys(alamethicin 1-17)4-NH2, tetramethicin, which was prepared by coupling several small fragments to tetraysine while attached to a solid support, showed an effective concentration dependence 2.7 times that of alamethicin. Other oligomeric pores are in preparation using aza-crown ether scaffolds. (JS)

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Document Details

Document Type
Technical Report
Publication Date
Nov 29, 1990
Accession Number
ADA229777

Entities

People

  • Garland R. Marshall

Organizations

  • University of Washington

Tags

Communities of Interest

  • C4I

DTIC Thesaurus Topics

  • Abstracts
  • Air Force
  • Amino Acids
  • Biological Sciences
  • Chemistry
  • Classification
  • Contracts
  • Crown Ethers
  • Electric Fields
  • Engineering
  • Military Research
  • Molecules
  • Oligomers
  • Peptides
  • Solid Phases
  • Systems Biology
  • Transitions

Fields of Study

  • Chemistry

Readers

  • Military Logistics and Supply Chain Management
  • Molecular and Cellular Biochemistry