Surface-Catalyzed Chemiluminescence

Abstract

Intense red emission peaking at 703 mm was observed when a heated metal wire was placed downstream of an O2 generator used in the chemical oxygen iodine laser (COIL) system. The O2 is produced by bubbling Cl2 through an alkaline solution of H2O2. Evidence has been found that this strong red emission requires the presence of both O2 and Cl2 in contact with a heated metal surface. Several metals have been used. The red emission spectrum is independent of the metal and the intensity is strongest for cooper. An attempt was made to observe laser action but no gain was detected. The identity of the species responsible for the strong red emission has not been established.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Dec 10, 1990
Accession Number
ADA230176

Entities

People

  • Richard Zare

Organizations

  • Stanford University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Aqueous Solutions
  • Chemical Lasers
  • Chemical Oxygen Iodine Lasers
  • Detectors
  • Emission
  • Emission Spectra
  • Emitters
  • Energy
  • Energy Transfer
  • Flow Rate
  • Lasers
  • Low Resolution
  • Measurement
  • Optomechanics
  • Oxygen
  • Partial Pressure
  • Spectra

Fields of Study

  • Physics

Readers

  • Combustion science or combustion engineering.
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Molecular Photonics/Laser Physics

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers