A Two-Dimensional Photochemical Model of the Troposphere

Abstract

An experiment using a time-dependent, two-dimensional photochemical model of the troposphere to model the vertical and zonal distribution of ozone and its precursors is presented. The experiment examines two cases. Case I simulates vertical transport due to diffusion and zonal transport due to advection, with surface emissions of ozone precursors in the center of the model domain representing an urban environment with light wind conditions favorable for the formation of ozone in concentrations greater than 80 parts per billion by volume (ppbv). In Case II, an elevated source of ozone and its precursors is introduced at the upstream boundary in order to investigate the role of advection of these chemical species on ozone concentrations. the first simulation produces surface ozone concentrations greater than 120 ppbv in the air above the urban area, and the second simulation produces an increase of 3 - 10 percent in this region. A comparison of Case I and Case II results shows that enhanced photochemical production of ozone due to the addition of ozone's precursors play an important role in this increase.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1990
Accession Number
ADA231163

Entities

People

  • Meade W. Carlson

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Biomedical
  • Energy and Power Technologies
  • Space

DTIC Thesaurus Topics

  • Alkenes
  • Boundary Layer
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Diffusion
  • Environmental Protection
  • Equations
  • Experimental Design
  • Heat Flux
  • High Pressure
  • Meteorological Phenomena
  • Meteorology
  • Standards
  • Two Dimensional
  • United States
  • Urban Areas

Fields of Study

  • Environmental science

Readers

  • Coastal Oceanography
  • Environmental Engineering
  • Polymer Science and Technology