Diphenylphosphide Derivatives of Bisneopentyl-Gallium and -Indium. Crystal and Molecular Structures of ((Me3CCH2)2GaPPh2)2 and ((Me3CCH2)2InPPh2)3

Abstract

The two compounds, (Me3CCH2) 2MPPh2 (M=Ga, In) have been prepared by metathetical reactions between (Me3CCH2)2MCl and KPPh2 and fully characterized. The characterization data include elemental analyses (C,H), melting points, IR, H and P NMR spectral studies, cryoscopic molecular weight studies in benzene solution and single crystal X-ray structural studies. The gallium compound exists as a dimer in benzene solution and in the solid state.

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Document Details

Document Type
Technical Report
Publication Date
Jan 18, 1991
Accession Number
ADA231237

Entities

People

  • James C Fettinger
  • Lisa A. Buttrey
  • Melvyn Rowen M.R. Churchill
  • Michael A. Banks
  • O. T. Beachley Jr.

Organizations

  • University at Buffalo

Tags

Communities of Interest

  • Ground and Sea Platforms

DTIC Thesaurus Topics

  • Alkanes
  • Carbon Carbon Composites
  • Cells
  • Chemical Synthesis
  • Chemistry
  • Diffraction
  • Diffractometers
  • Elements
  • Materials
  • Measurement
  • Military Research
  • Molecular Structure
  • Molecules
  • Spectra
  • United States
  • X Rays
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry

Technology Areas

  • Microelectronics