The Octanol/Water Partition Coefficient of Methylmercuric Chloride and Methylmercuric Hydroxide in Pure Water and Salt Solutions

Abstract

The 1-octanol/water partition coefficient (Kow) of methylmercury was determined at pH7 in water and in aqueous solutions ranging from 0.0003 to 0. 6000 M in sodium chloride. It was also determined over a pH range of 2 to 10 with a fixed sodium chloride concentration of 0.00045 M. In these experiments, Kow was seen to increase with increasing chloride concentrations in the range 0. 0 to 0.075 M and to decrease with increasing pH above 7. Results were similar whether low levels of methylmercuric chloride or methylmercuric hydroxide were used as the starting materials. Partitioning was not affected by changes in ionic strength.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1991
Accession Number
ADA231763

Entities

People

  • David H. Rosenblatt
  • Karen A. Bostian
  • Michael A. Major

Organizations

  • United States Army Biological Warfare Laboratories

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Aquatic Organisms
  • Aqueous Solutions
  • Biomedical Research
  • Chemical Properties
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Coefficients
  • Computer Programs
  • Correlation Analysis
  • Ecotoxicology
  • Hydroxides
  • New York
  • Saline Solution
  • Salinity
  • Sodium Compounds
  • Water

Fields of Study

  • Environmental science

Readers

  • Analytical Chemistry